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01
used to express affection, empathy, or endearment
02
used to express disappointment or annoyance in response to an unsatisfactory or unfortunate situation
Example
Aw, look at the puppy sleeping in the sunbeam!
Aw, you brought me flowers?
Aw, you hurt your knee?
Aw, I forgot to submit my application before the deadline.
Aw, I didn't get the grade I was hoping for on the test.